全文获取类型
收费全文 | 3046篇 |
免费 | 273篇 |
国内免费 | 322篇 |
专业分类
化学 | 281篇 |
晶体学 | 2篇 |
力学 | 316篇 |
综合类 | 116篇 |
数学 | 2333篇 |
物理学 | 593篇 |
出版年
2024年 | 5篇 |
2023年 | 15篇 |
2022年 | 36篇 |
2021年 | 38篇 |
2020年 | 62篇 |
2019年 | 43篇 |
2018年 | 56篇 |
2017年 | 72篇 |
2016年 | 101篇 |
2015年 | 63篇 |
2014年 | 124篇 |
2013年 | 191篇 |
2012年 | 172篇 |
2011年 | 205篇 |
2010年 | 184篇 |
2009年 | 224篇 |
2008年 | 218篇 |
2007年 | 240篇 |
2006年 | 211篇 |
2005年 | 173篇 |
2004年 | 148篇 |
2003年 | 157篇 |
2002年 | 116篇 |
2001年 | 111篇 |
2000年 | 90篇 |
1999年 | 92篇 |
1998年 | 97篇 |
1997年 | 71篇 |
1996年 | 58篇 |
1995年 | 34篇 |
1994年 | 37篇 |
1993年 | 31篇 |
1992年 | 31篇 |
1991年 | 17篇 |
1990年 | 10篇 |
1989年 | 13篇 |
1988年 | 10篇 |
1987年 | 6篇 |
1986年 | 9篇 |
1985年 | 12篇 |
1984年 | 9篇 |
1983年 | 8篇 |
1982年 | 11篇 |
1981年 | 8篇 |
1980年 | 10篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1971年 | 1篇 |
1936年 | 2篇 |
排序方式: 共有3641条查询结果,搜索用时 31 毫秒
91.
主要研究当两种类型的参数扰动时,多目标最优化问题中恰当有效解的稳定性.在点集映射的连续性意义下,分析讨论这种稳定性问题并分别给出引起扰动的两参数u,v所对应的点集映射Q1(u)和Q2(v),同时严格证明了在两个闭凸锥U,V上Q1(u)和Q2(v)的连续性定理.最后,通过附注对其进行补充和改进. 相似文献
92.
在实Hausdorff拓扑线性空间中研究了含参弱向量均衡问题的适定性.证明了在适当条件下由近似网定义的含参适定性等价于近似解映射的上半连续性,并给出了所研究问题各种适定的充分性条件. 相似文献
93.
In two real Banach spaces, we shall present two conditions, under one of which each nonexpansive mapping must be an isometry. 相似文献
94.
95.
A new time-of-flight (TOF) momentum and energy mapping system is proposed. The system consists of two sub-regions with different axial uniform decelerating field. Two position-sensitive detectors (PSDs) on opposite side of the tube are used for the detection of electrons with different axial motion length due to their initial energy ? and emission angle θ. A non-monotonic dependence of energy-resolving performance on electron initial energy can be achieved by choosing appropriate electric field deceleration for these two sub-regions, which forms an “energy resolution probe” possessing a higher level of energy resolution than that of lower energy part. And the local resolution in the probe region could be specifically enhanced while the other parts of all the detection range do not change so much. It is verified by the illustrating example with relative energy resolution Δ?/? smaller than 0.5% for electron energy in probe range from 36 eV to 45 eV. 相似文献
96.
97.
In the previous work, it was shown that, in supersymmetric (matrix) discretized quantum mechanics, inclusion of an external field twisting the boundary condition of fermions enables us to discuss spontaneous breaking of supersymmetry (SUSY) in the path-integral formalism in a well-defined way. In the present work, we continue investigating the same systems from the points of view of localization and Nicolai mapping. The localization is studied by changing of integration variables in the path integral, which is applicable whether or not SUSY is explicitly broken. We examine in detail how the integrand of the partition function with respect to the integral over the auxiliary field behaves as the auxiliary field vanishes, which clarifies a mechanism of the localization. In SUSY matrix models, we obtain a matrix-model generalization of the localization formula. In terms of eigenvalues of matrix variables, we observe that eigenvalues' dynamics is governed by balance of attractive force from the localization and repulsive force from the Vandermonde determinant. The approach of the Nicolai mapping works even in the presence of the external field. It enables us to compute the partition function of SUSY matrix models for finite N (N is the rank of matrices) with arbitrary superpotential at least in the leading nontrivial order of an expansion with respect to the small external field. We confirm the restoration of SUSY in the large-N limit of a SUSY matrix model with a double-well scalar potential observed in the previous work. 相似文献
98.
The characterization of novel metal reinforced electro-dialysis ion exchange membranes, for water desalination, by attenuated total reflectance Fourier transform infrared spectroscopy mapping is presented in this paper. The surface of the porous stainless steel fibre meshes was treated in order to enhance the amount of surface oxide groups and increase the material hydrophilicity. Then, the metal membranes were functionalized through a sol–gel reaction with silane coupling agents to enhance the affinity with the ion exchange resins and avoid premature metal oxidation due to redox reactions at the metal–polymer interface. Polished cross sections of the composite membranes embedded into an epoxy resin revealed interfaces between metallic frameworks and the silane layer at the interface with the ion exchange material. The morphology of the metal–polymer interface was investigated with scanning electron microscopy and Fourier transform infrared micro-spectroscopy. Fourier transform infrared mapping of the interfaces was performed using the attenuated total reflectance mode on the polished cross-sections at the Australian Synchrotron. The nature of the interface between the metal framework and the ion exchange resin was shown to be homogeneous and the coating thickness was found to be around 1 μm determined by Fourier transform infrared micro-spectroscopy mapping. The impact of the coating on the properties of the membranes and their potential for water desalination by electro-dialysis are also discussed. 相似文献
99.
Michael Biacchi Ricky Bhajun Nassur Saïd Alain Beck Yannis Nicolas François Emmanuelle Leize‐Wagner 《Electrophoresis》2014,35(20):2986-2995
mAbs are highly complex proteins that present a wide range of microheterogeneity that requires multiple analytical methods for full structure assessment and quality control. As a consequence, the characterization of mAbs on different levels is particularly product‐ and time‐consuming. CE‐MS couplings, especially to MALDI, appear really attractive methods for the characterization of biological samples. In this work, we report the last instrumental development and performance of the first totally automated off‐line CE‐UV/MALDI‐MS/MS. This interface is based on the removal of the original UV cell of the CE apparatus, modification of the spotting device geometry, and creation of an integrated delivery matrix system. The performance of the method was evaluated with separation of five intact proteins and a tryptic digest mixture of nine proteins. Intact protein application shows the acquisition of electropherograms with high resolution and high repeatability. In the peptide mapping approach, a total number of 154 unique identified peptides were characterized using MS/MS spectra corresponding to average sequence coverage of 64.1%. Comparison with NanoLC/MALDI‐MS/MS showed complementarity at the peptide level with an increase of 42% when using CE/MALDI‐MS coupling. Finally, this work represents the first analysis of intact mAb charge variants by CZE using an MS detection. Moreover, using a peptide mapping approach CE‐UV/MALDI‐MS/MS fragmentation allowed 100% sequence coverage of the light chain and 92% of the heavy chain, and the separation of four major glycosylated peptides and their structural characterization. 相似文献
100.
C. P. East W. O. S. Doherty C. M. Fellows H. Yu 《Surface and interface analysis : SIA》2011,43(9):1231-1239
Fouling of heat exchanger surfaces during sugar manufacture reduces productivity and increases energy demand. This study characterizes a deposit (including its internal structure) formed in a sugar factory's evaporator unit using a variety of X‐ray diffraction and scanning electron microscopy techniques (including X‐ray powder diffraction, X‐ray fluorescence, elemental mapping with energy dispersive spectroscopy and backscattered electron imaging). Calcium sulfate dihydrate, calcium oxalate mono‐ and dihydrate, hydroxyapatite, amorphous silica and organic matter are present in the deposit. The composition of the deposit (which contains three layers) varies along the height of the tube. There are noticeable differences in the composition and porosity among the layers in the deposit. A porous structure consisting of a mixture of amorphous silica, calcium oxalate dihydrate and organic matter is attached to the surface of the deposit in contact with sugar juice, while a denser morphology of amorphous silica and hydroxyapatite is attached to the tube wall. Elemental mapping identifies an association between Si, Al, Mg, Fe and O, suggesting the presence of a silicate compound as a minor component in the deposit. An attempt is made to rationalize the formation of the observed phases. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献